Looks like currently Zuora does not allow to deactivate/ revoke a user if the status is pending activation. The work around suggested by support via ticket # 61582 is that we should update the email to our own or another email which we can access to first activate the account and then deactivate.
This seems coutner intuitive and a security risk. As a Zuora admin we should be able to deactivate/ revoke access at any given time.
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